Bis(4-methylmorpholin-4-ium) tetrabromidozincate(II)
نویسندگان
چکیده
The title compound, (C(5)H(12)NO)(2)[ZnBr(4)], was synthesized by hydro-thermal reaction of ZnBr(2) with 4-methyl-morpholine in a HBr/distilled water solution. Each of the two independent cations exhibits a chair conformation; the anion deviates slightly from an tetrahedral configuration. The Zn-Br distances in the anion are in the range of 2.3996 (9)-2.4247 (9) Å. All of the amine H atoms are involved in bifurcated inter-molecular N-H⋯Br hydrogen bonds, building up a trimer.
منابع مشابه
catena-Poly[4-methylmorpholin-4-ium [[dichloridobismuth(III)]-di-μ-chlorido]]
The asymmetric unit of the title complex, {(C(5)H(12)NO)[BiCl(4)]}(n), contains two bridging and two cis non-bridging chloride ligands coordinated to a central Bi(III) atom, and one 4-methyl-morpholin-4-ium cation. The Bi(III) atoms are linked by the bridging chloride ligands into linear chains parallel to the c axis. The chloride ions create a pseudo-octa-hedral geometry about each Bi(III) ato...
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